Take That and Plan B will also be wowing the crowds at the bash on 15 February.
Pop megastar Rihanna never fails to impress with her raunchy performances, and we'll be hoping for a Tinie/RiRi duet.
Manband Take That will be gracing the Brits stage for the first time in 16 years.
Other nominees include Take That, Katy Perry, Ellie Goulding, Olly Murs, Plan B, Mumford and Sons, The XX and Jessie J.
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